JREF Homepage Swift Blog Events Calendar $1 Million Paranormal Challenge The Amaz!ng Meeting Useful Links Support Us
James Randi Educational Foundation JREF Forum
Forum Index Register Members List Events Mark Forums Read Help

Go Back   JREF Forum » General Topics » Science, Mathematics, Medicine, and Technology
Click Here To Donate

Notices


Welcome to the JREF Forum, where we discuss skepticism, critical thinking, the paranormal and science in a friendly but lively way. You are currently viewing the forum as a guest, which means you are missing out on discussing matters that are of interest to you. Please consider registering so you can gain full use of the forum features and interact with other Members. Registration is simple, fast and free! Click here to register today.

Tags fuel cell , hydrogen , hydrogen fuel , microbes

Reply
Old 20th September 2011, 12:45 PM   #1
catsmate1
Philosopher
 
catsmate1's Avatar
 
Join Date: Apr 2007
Location: Dublin (the one in Ireland)
Posts: 7,140
Self-powered hydrogen generation from bacteria

According to this interesting article in the US Proceedings of the National Academy of Sciences US researchers have managed to generate hydrogen by bacterial action without needing an external power source. If correct this is a major breakthrough in practical hydrogen fuel production, though currently cost is too great for commercial use.
There's a good article on the paper on the BBC website.

Originally Posted by Abstract
There is a tremendous source of entropic energy available from the salinity difference between river water and seawater, but this energy has yet to be efficiently captured and stored. Here we demonstrate that H2 can be produced in a single process by capturing the salinity driven energy along with organic matter degradation using exoelectrogenic bacteria. Only five pairs of seawater and river water cells were sandwiched between an anode, containing exoelectrogenic bacteria, and a cathode, forming a microbial reverse-electrodialysis electrolysis cell. Exoelectrogens added an electrical potential from acetate oxidation and reduced the anode overpotential, while the reverse electrodialysis stack contributed 0.5–0.6 V at a salinity ratio (seawater:river water) of 50. The H2 production rate increased from 0.8 to 1.6 m3-H2/m3-anolyte/day for seawater and river water flow rates ranging from 0.1 to 0.8 mL/ min. H2 recovery, the ratio of electrons used for H2 evolution to electrons released by substrate oxidation, ranged from 72% to 86%. Energy efficiencies, calculated from changes in salinities and the loss of organic matter, were 58% to 64%. By using a relatively small reverse electrodialysis stack (11 membranes), only ∼1% of the produced energy was needed for pumping water. Although Pt was used on the cathode in these tests, additional tests with a nonprecious metal catalyst (MoS2) demonstrated H2 production at a rate of 0.8 m3/m3/d and an energy efficiency of 51%. These results show that pure H2 gas can efficiently be produced from virtually limitless supplies of seawater and river water, and biodegradable organic matter.
catsmate1 is offline   Quote this post in a PM   Nominate this post for this month's language award Copy a direct link to this post Reply With Quote Back to Top
Old 20th September 2011, 10:58 PM   #2
Mikemcc
Muse
 
Join Date: Dec 2009
Posts: 958
By not requiring an external power source they are meaning that they don't need to apply a current across the cells to generate the hydrogen. There will still be a requirement to run pumps, cultivate, and maintain the organisms, etc.
Mikemcc is offline   Quote this post in a PM   Nominate this post for this month's language award Copy a direct link to this post Reply With Quote Back to Top
Old 20th September 2011, 11:34 PM   #3
phildonnia
Master Poster
 
phildonnia's Avatar
 
Join Date: Oct 2001
Location: Sac'to CA
Posts: 2,339
I didn't quite understand the sciencey bit. Where does the energy come from?
phildonnia is offline   Quote this post in a PM   Nominate this post for this month's language award Copy a direct link to this post Reply With Quote Back to Top
Old 21st September 2011, 12:10 AM   #4
nvidiot
Botanical Jedi
 
nvidiot's Avatar
 
Join Date: Apr 2010
Posts: 1,793
Iiiiiiinteresting.

I'm a bit confused as well, but the BBC link says:

Quote:
The MECs use something called "reverse electrodialysis" (RED), which refers to the energy gathered from the difference in salinity, or salt content, between saltwater and freshwater.
ETA: wiki link for MEC (Microbial Electrolysis Cell)

ETA2: A good diagram for the process is here on wiki too
__________________
www.horsemen-gaming.com

Last edited by nvidiot; 21st September 2011 at 12:14 AM.
nvidiot is offline   Quote this post in a PM   Nominate this post for this month's language award Copy a direct link to this post Reply With Quote Back to Top
Old 21st September 2011, 12:14 AM   #5
Darat
Lackey
Administrator / JREF Forum Liaison
 
Darat's Avatar
 
Join Date: Aug 2001
Location: South East, UK
Posts: 64,804
Originally Posted by phildonnia View Post
I didn't quite understand the sciencey bit. Where does the energy come from?
Yeah - come on big brains explain to us where the magic comes from! Also as others have mentioned there would be be energy inputs into such a system such as the pumps and so on - is it likely that the net output would be positive when those energy costs are taken into account or is this one that would still rely on being manufactured using non-renewable energy sources?
__________________
If it were all so simple! If only there were evil people somewhere insidiously committing evil deeds, and it were necessary only to separate them from the rest of us and destroy them. But the line dividing good and evil cuts through the heart of every human being. And who is willing to destroy a piece of his own heart? -
Aleksandr Solzhenitsyn 1918-2008
Darat is offline   Quote this post in a PM   Nominate this post for this month's language award Copy a direct link to this post Reply With Quote Back to Top
Old 21st September 2011, 01:08 AM   #6
bjornart
Master Poster
 
bjornart's Avatar
 
Join Date: Nov 2002
Posts: 2,398
Originally Posted by phildonnia View Post
I didn't quite understand the sciencey bit. Where does the energy come from?
From the quote in the OP:
Quote:
Here we demonstrate that H2 can be produced in a single process by capturing the salinity driven energy along with organic matter degradation using exoelectrogenic bacteria.
Salinity differences and stuff rotting.
__________________
Well, I DON'T CARE WHAT YOU LIKE TO BELIEVE, GODDAMMIT! I DEAL IN THE FACTS!
-Cecil Adams
bjornart is offline   Quote this post in a PM   Nominate this post for this month's language award Copy a direct link to this post Reply With Quote Back to Top
Old 21st September 2011, 02:14 AM   #7
catsmate1
Philosopher
 
catsmate1's Avatar
 
Join Date: Apr 2007
Location: Dublin (the one in Ireland)
Posts: 7,140
Originally Posted by Darat View Post
Yeah - come on big brains explain to us where the magic comes from! Also as others have mentioned there would be be energy inputs into such a system such as the pumps and so on - is it likely that the net output would be positive when those energy costs are taken into account or is this one that would still rely on being manufactured using non-renewable energy sources?
Yes there will be extraction/containment/cultivation energy costs. The process is analogous to fermentation of sugar to alcohols, provide feedstock and the micro-organisms will produce the hydrogen; the output gas will need to be pumped and compressed. With development the process should be cheaper than current methods for hydrogen production, steam reforming requires fossil fuels and heat and electrolysis is very energy intensive.
It's a start, not a solution.
catsmate1 is offline   Quote this post in a PM   Nominate this post for this month's language award Copy a direct link to this post Reply With Quote Back to Top
Old 21st September 2011, 02:59 AM   #8
Lukraak_Sisser
Graduate Poster
 
Join Date: Aug 2009
Posts: 1,623
Originally Posted by Darat View Post
Yeah - come on big brains explain to us where the magic comes from! Also as others have mentioned there would be be energy inputs into such a system such as the pumps and so on - is it likely that the net output would be positive when those energy costs are taken into account or is this one that would still rely on being manufactured using non-renewable energy sources?
Part of it could I suppose be easily linked to a large freshwater pump system containing degredable organic matter present in all large cities (ie, the sewer system)
The sewage would provide the energy for the bacteria to grow and produce H2.
The salt water is harder. For seaside cities this could quite conceivably be a process with a net energy gain, but I suspect that pumping seawater any real distance negates such a gain.
Of course if treating sewage in seaside cities becomes an energy producer rather than consumer this would in the long run benefit any city hooked up to the same grid.
Lukraak_Sisser is offline   Quote this post in a PM   Nominate this post for this month's language award Copy a direct link to this post Reply With Quote Back to Top
Old 21st September 2011, 03:20 AM   #9
nvidiot
Botanical Jedi
 
nvidiot's Avatar
 
Join Date: Apr 2010
Posts: 1,793
Wouldn't it be quite easy to make salt water in places that have none, by just adding salt to the fresh water? A lot easier than moving salt water around.
__________________
www.horsemen-gaming.com
nvidiot is offline   Quote this post in a PM   Nominate this post for this month's language award Copy a direct link to this post Reply With Quote Back to Top
Old 21st September 2011, 04:41 AM   #10
bjornart
Master Poster
 
bjornart's Avatar
 
Join Date: Nov 2002
Posts: 2,398
Originally Posted by nvidiot View Post
Wouldn't it be quite easy to make salt water in places that have none, by just adding salt to the fresh water? A lot easier than moving salt water around.
Salt may be cheap, but I doubt it's so cheap that would make sense.
__________________
Well, I DON'T CARE WHAT YOU LIKE TO BELIEVE, GODDAMMIT! I DEAL IN THE FACTS!
-Cecil Adams
bjornart is offline   Quote this post in a PM   Nominate this post for this month's language award Copy a direct link to this post Reply With Quote Back to Top
Old 21st September 2011, 06:03 AM   #11
BenBurch
Gatekeeper of The Left
 
BenBurch's Avatar
 
Join Date: Sep 2007
Location: The Universe 35.2 ms ahead of this one.
Posts: 32,222
Bacteria don't just live on nothing. They need an energy source. For most bacteria this is chemical energy derived from their environment. For photosynthetic or radiosynthetic bacteria, an external energy source is captured and converted into chemical energy for the cell to use.

Nothing here has shown what they eat.
BenBurch is offline   Quote this post in a PM   Nominate this post for this month's language award Copy a direct link to this post Reply With Quote Back to Top
Old 21st September 2011, 06:39 AM   #12
richardm
Philosopher
 
richardm's Avatar
 
Join Date: Aug 2001
Posts: 9,270
Originally Posted by BenBurch View Post
Nothing here has shown what they eat.
It's bacteria all the way down.
__________________
Rimmer: Look at her! Magnificent woman! Very prim, very proper, almost austere. Some people took her for cold, thought she was aloof. Not a bit of it. She just despised fools. Quite tragic, really, because otherwise I think we'd have got on famously.
richardm is offline   Quote this post in a PM   Nominate this post for this month's language award Copy a direct link to this post Reply With Quote Back to Top
Old 21st September 2011, 06:45 AM   #13
nvidiot
Botanical Jedi
 
nvidiot's Avatar
 
Join Date: Apr 2010
Posts: 1,793
Quote:
Bacteria don't just live on nothing. They need an energy source. For most bacteria this is chemical energy derived from their environment. For photosynthetic or radiosynthetic bacteria, an external energy source is captured and converted into chemical energy for the cell to use.

Nothing here has shown what they eat.

Of course they don't live on nothing Ben, the paper apparently suggests wastewater as the organic material source. The BBC link in the OP has a quote from the authors.
__________________
www.horsemen-gaming.com

Last edited by nvidiot; 21st September 2011 at 06:46 AM.
nvidiot is offline   Quote this post in a PM   Nominate this post for this month's language award Copy a direct link to this post Reply With Quote Back to Top
Old 21st September 2011, 07:21 AM   #14
Cuddles
Decoy
Moderator
 
Cuddles's Avatar
 
Join Date: Jul 2006
Location: A magical land full of pink fluffy sheeps and bunnies
Posts: 16,597
Originally Posted by phildonnia View Post
I didn't quite understand the sciencey bit. Where does the energy come from?
http://en.wikipedia.org/wiki/Reverse_electrodialysis

Basically, when you dissolve something in water, energy is either used or released. So when you put two volumes of water with different concentration next to each other you get an energy gradient, and like any gradient it can be exploited to do work, at least in theory. It's essentially the same principle as two different metals producing a voltage when put together.

From the Wiki article, it appears this principle is already being looked into as a means of producing electricity. This new research is instead looking at using it to produce hydrogen directly, without the inefficiencies that would be present from first making electricity and then using that for electrolysis. The main question is likely to be how efficient this method actually is, and whether it would actually be better than just producing electricity without the bacteria getting involved.
__________________
I am not a little teapot.
Cuddles is offline   Quote this post in a PM   Nominate this post for this month's language award Copy a direct link to this post Reply With Quote Back to Top
Old 21st September 2011, 07:36 AM   #15
Cainkane1
Philosopher
 
Cainkane1's Avatar
 
Join Date: Jul 2005
Location: The great American southeast
Posts: 7,198
What the world needs is a lot of cheap power. This is very interesting but can we put this to use on a large scale and can the ordinary citizen afford it?
__________________
If at first you don't succeed try try again. Then if you fail to succeed to Hell with that. Try something else.
Cainkane1 is offline   Quote this post in a PM   Nominate this post for this month's language award Copy a direct link to this post Reply With Quote Back to Top
Old 21st September 2011, 08:04 AM   #16
bjornart
Master Poster
 
bjornart's Avatar
 
Join Date: Nov 2002
Posts: 2,398
Originally Posted by Cainkane1 View Post
What the world needs is a lot of cheap power. This is very interesting but can we put this to use on a large scale and can the ordinary citizen afford it?
We won't know until we try.
__________________
Well, I DON'T CARE WHAT YOU LIKE TO BELIEVE, GODDAMMIT! I DEAL IN THE FACTS!
-Cecil Adams
bjornart is offline   Quote this post in a PM   Nominate this post for this month's language award Copy a direct link to this post Reply With Quote Back to Top
Old 21st September 2011, 04:34 PM   #17
phildonnia
Master Poster
 
phildonnia's Avatar
 
Join Date: Oct 2001
Location: Sac'to CA
Posts: 2,339
Originally Posted by Cuddles View Post
Ok, so basically, fresh water has higher potential than salt water?
phildonnia is offline   Quote this post in a PM   Nominate this post for this month's language award Copy a direct link to this post Reply With Quote Back to Top
Old 22nd September 2011, 06:06 AM   #18
BenBurch
Gatekeeper of The Left
 
BenBurch's Avatar
 
Join Date: Sep 2007
Location: The Universe 35.2 ms ahead of this one.
Posts: 32,222
Originally Posted by nvidiot View Post
Of course they don't live on nothing Ben, the paper apparently suggests wastewater as the organic material source. The BBC link in the OP has a quote from the authors.
Ah, OK. That is a very limited resource, believe it or not. You might think that well, there is a lot of crap in the world, but when you look at the energy content of a city's sewage, it does not amount to much in terms of the energy the city uses.
BenBurch is offline   Quote this post in a PM   Nominate this post for this month's language award Copy a direct link to this post Reply With Quote Back to Top
Old 22nd September 2011, 08:18 AM   #19
dlorde
Illuminator
 
dlorde's Avatar
 
Join Date: Apr 2007
Posts: 4,647
Originally Posted by Darat View Post
Yeah - come on big brains explain to us where the magic comes from! Also as others have mentioned there would be be energy inputs into such a system such as the pumps and so on - is it likely that the net output would be positive when those energy costs are taken into account or is this one that would still rely on being manufactured using non-renewable energy sources?
There's a partial answer in the quoted abstract:

Quote:
By using a relatively small reverse electrodialysis stack (11 membranes), only ∼1% of the produced energy was needed for pumping water.
__________________
Simple probability tells us that we should expect coincidences, and simple psychology tells us that we'll remember the ones we notice...
dlorde is offline   Quote this post in a PM   Nominate this post for this month's language award Copy a direct link to this post Reply With Quote Back to Top
Old 22nd September 2011, 08:30 AM   #20
Cuddles
Decoy
Moderator
 
Cuddles's Avatar
 
Join Date: Jul 2006
Location: A magical land full of pink fluffy sheeps and bunnies
Posts: 16,597
Originally Posted by phildonnia View Post
Ok, so basically, fresh water has higher potential than salt water?
Pretty much. It's the same basic principle as putting salt on a slug to kill it, or why salt and sugar work as preservatives - water will tend to flow through a membrane from high concentration to low concentration, even when there are other pressures trying to stop it. The slug keeps its water inside just fine, but put salt on it and the osmotic pressure is enough to suck it out. The same sucking can be harnessed to produce electricity or, in this case, to directly produce hydrogen, or in other ways such as simply acting as a water pump.
__________________
I am not a little teapot.
Cuddles is offline   Quote this post in a PM   Nominate this post for this month's language award Copy a direct link to this post Reply With Quote Back to Top
Old 22nd September 2011, 08:51 AM   #21
phildonnia
Master Poster
 
phildonnia's Avatar
 
Join Date: Oct 2001
Location: Sac'to CA
Posts: 2,339
Ok, so it ultimately runs on fresh water. Glad to hear we have an energy supply that uses an inexhaustible, infinite source.
phildonnia is offline   Quote this post in a PM   Nominate this post for this month's language award Copy a direct link to this post Reply With Quote Back to Top
Old 22nd September 2011, 09:12 AM   #22
Buckaroo
Graduate Poster
 
Buckaroo's Avatar
 
Join Date: Feb 2006
Location: Washington, D.C.
Posts: 1,718
Cool. During my days at the NSF back in 2004 I was involved in a similar story, also with Bruce Logan as an investigator: http://www.nsf.gov/news/news_summ.jsp?cntn_id=100337
__________________
"You ask me do I love you... does the pope live in the woods? Quad Erat Demonstrandum, baby... "
"Oh! You speak French!" -- Airhead, by Thomas Dolby

"When you're slapped you'll take it and like it." -- Sam Spade

Last edited by Buckaroo; 22nd September 2011 at 09:14 AM.
Buckaroo is offline   Quote this post in a PM   Nominate this post for this month's language award Copy a direct link to this post Reply With Quote Back to Top
Old 22nd September 2011, 03:04 PM   #23
nvidiot
Botanical Jedi
 
nvidiot's Avatar
 
Join Date: Apr 2010
Posts: 1,793
Originally Posted by phildonnia View Post
Ok, so it ultimately runs on fresh water. Glad to hear we have an energy supply that uses an inexhaustible, infinite source.
There is substantial amounts of energy available in salinity gradients, the trick is how to liberate it. This appears to be a substantial improvement in efficiency, which will likely spur more investment and development, and hopefully more efficiency and so on.

Quote:
BenBurch

Ah, OK. That is a very limited resource, believe it or not. You might think that well, there is a lot of crap in the world, but when you look at the energy content of a city's sewage, it does not amount to much in terms of the energy the city uses.
City sewages wouldn't be the only domestic source, farm wastes, household organic wastes, heck all kinds of organic material is wasted by human civilisation and would be relatively easy to recover if sufficiently valued. I'm sure they'll expand potential biological agents using all kinds of neat byproducts as nutrient sources. Genetic engineering could provide some novel solutions too.

This is not the solution to our energy issues, and won't be for decades even if it can be appropriately scaled for large loads. That said, we could be looking at a large and untapped energy source and given the situation humanity finds itself in, it would be quite wise to invest in such ideas.
__________________
www.horsemen-gaming.com
nvidiot is offline   Quote this post in a PM   Nominate this post for this month's language award Copy a direct link to this post Reply With Quote Back to Top
Old 23rd September 2011, 12:19 AM   #24
phildonnia
Master Poster
 
phildonnia's Avatar
 
Join Date: Oct 2001
Location: Sac'to CA
Posts: 2,339
Originally Posted by nvidiot View Post
There is substantial amounts of energy available in salinity gradients, the trick is how to liberate it. This appears to be a substantial improvement in efficiency, which will likely spur more investment and development, and hopefully more efficiency and so on.
Don't get me wrong; I'm glad to hear that there is another source of energy that we can add to the mix in the future. We should be cautious not to assume that the magic bullet for our increasing energy demands has been found.
phildonnia is offline   Quote this post in a PM   Nominate this post for this month's language award Copy a direct link to this post Reply With Quote Back to Top
Old 23rd September 2011, 10:10 AM   #25
CORed
Illuminator
 
Join Date: Dec 2008
Posts: 4,295
Originally Posted by BenBurch View Post
Ah, OK. That is a very limited resource, believe it or not. You might think that well, there is a lot of crap in the world, but when you look at the energy content of a city's sewage, it does not amount to much in terms of the energy the city uses.
A lot of sewage plants capture methane produced by anaerobic digesters and use it to power generators. In most cases, I don't believe this produces as much energy as the sewage plant uses.
CORed is offline   Quote this post in a PM   Nominate this post for this month's language award Copy a direct link to this post Reply With Quote Back to Top
Old 23rd September 2011, 10:13 AM   #26
aggle-rithm
Ardent Formulist
 
aggle-rithm's Avatar
 
Join Date: Jun 2005
Location: Austin, TX
Posts: 14,156
I, for one, welcome our new hydrogen-producing bacteria overlords.
__________________
To understand recursion, you must first understand recursion.

Woo's razor: Never attribute to stupidity that which can be adequately explained by aliens.
aggle-rithm is offline   Quote this post in a PM   Nominate this post for this month's language award Copy a direct link to this post Reply With Quote Back to Top
Reply

JREF Forum » General Topics » Science, Mathematics, Medicine, and Technology

Bookmarks

Thread Tools

Posting Rules
You may not post new threads
You may not post replies
You may not post attachments
You may not edit your posts

BB code is On
Smilies are On
[IMG] code is On
HTML code is Off
Forum Jump


All times are GMT -7. The time now is 10:05 PM.
Powered by vBulletin. Copyright ©2000 - 2013, Jelsoft Enterprises Ltd.
© 2001-2012, James Randi Educational Foundation. All Rights Reserved.

Disclaimer: Messages posted in the Forum are solely the opinion of their authors.